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dc.contributor.authorSalifoglou, Athanasios
dc.contributor.authorPapadopoulos, Theodoros
dc.contributor.authorReimann, M. K.
dc.contributor.authorPöttgen, R.
dc.contributor.authorSalifoglou, A.
dc.contributor.authorMatsia, S.
dc.contributor.authorKaoulla, A.
dc.contributor.authorMenelaou, M.
dc.contributor.authorHatzidimitriou, A.
dc.date.accessioned2021-11-25T10:12:59Z
dc.date.available2021-11-25T10:12:59Z
dc.date.issued2021-11-10
dc.identifierhttps://chesterrep.openrepository.com/bitstream/handle/10034/626436/1-s2.0-S0277538721005593-main.pdf?sequence=1
dc.identifier.citationMatsia, S., Kaoulla, A., Menelaou, M., Hatzidimitriou, A., Papadopoulos, T., Reimann, M. K., Pöttgen, R., & Salifoglou, A. (2021). Structural speciation in chemical reactivity profiling of binary-ternary systems of Ni(II) with iminodialcohol and aromatic chelators. Polyhedron, 115577. https://doi.org/https://doi.org/10.1016/j.poly.2021.115577en_US
dc.identifier.issn0277-5387
dc.identifier.doi10.1016/j.poly.2021.115577
dc.identifier.urihttp://hdl.handle.net/10034/626436
dc.description.abstractThe importance of structural speciation in the control of chemical reactivity in Ni(II) binary-ternary systems, involving (O,O,N)-containing substrates (1,1’-iminodi-2-propanol), and aromatic chelators (2,2’-bipyridine, 1,10-phenanthroline), prompted the systematic synthesis of new crystalline materials characterized by elemental analysis, FT-IR, UV-Visible, Luminescence, TGA, magnetic susceptibility, and X-ray crystallography. The structures contain mononuclear octahedral assemblies, the lattice architecture of which exemplifies reaction conditions under which conformational variants and solvent-associated lattice-imposed complexes are assembled. Transformations between complex species denote their association with reactivity pathways, suggesting alternate synthetic methodologies for their isolation. Theoretical work (Hirshfeld, Electrostatic Potential, DFT) signifies the impact of crystal structure on energy profiles of the generated species. The arisen physicochemical profiles of all compounds portray a well-configured interwoven network of pathways, projecting strong connection between structural speciation and Ni(II) reactivity patterns in organic-solvent media. The collective results provide well-defined parameterized profiles, poised to influence the synthesis of new Ni(II)-iminodialcohol materials with specified structural-magneto-optical properties.en_US
dc.publisherElsevieren_US
dc.relation.urlhttps://www.sciencedirect.com/science/article/pii/S0277538721005593en_US
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/en_US
dc.subjectnickel complex synthesisen_US
dc.subjectiminodialcohol liganden_US
dc.subjectstructure elucidationen_US
dc.subjectmagnetic propertiesen_US
dc.subjectchemical reactivity patternsen_US
dc.titleStructural speciation in chemical reactivity profiling of binary-ternary systems of Ni(II) with iminodialcohol and aromatic chelatorsen_US
dc.typeArticleen_US
dc.contributor.departmentAristotle University of Thessaloniki; University of Chester; Universität Münster; Cyprus University of Technologyen_US
dc.identifier.journalPolyhedronen_US
or.grant.openaccessYesen_US
rioxxterms.funderUnfundeden_US
rioxxterms.identifier.projectUnfundeden_US
rioxxterms.versionAMen_US
rioxxterms.versionofrecord10.1016/j.poly.2021.115577en_US
rioxxterms.licenseref.startdate2023-11-10
dcterms.dateAccepted2021-11-03
rioxxterms.publicationdate2021-11-10
dc.date.deposited2021-11-25en_US
dc.indentifier.issn0277-5387en_US


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